As Mad has posted his entire collection with updates, I suppose I should to! So here it is:
dvd
1. Akira New version thats just been released had the original and the digitally remastered versions on it.
2. Apple seed
3. Black jack
4. Blood:the last vampire
5. Blue gender disc1
6. Ghost in the shell
7. Goglo 13
8. Macross Plus box set (voluems 1+2, 3+4 and the movie )
9. Metropolis
10. Neon Genesis Evangelion: perfect collect, all 8 disc's in the collection
11. NGE: death and rebirth
12. NGE: The end of evangelion
13. Ninja scroll
14. Noir: Vol. 1: Shades of Darkness
15. Perfect Blue
16. Princess mononoke
17. Shadow skill
18. Street Fighter 2
19. Street fighter Alpha
20. The castle of Cagliostro
21. Urotsukidoji
22. X
23. Transformers orginal 16 episodes
24. Transformers the movie

Also have on preorder:

25. Spy Of Darkness
26. Mission Of Darkness
27. Idol Of Darkness
28. Alien From Darkness

Now recived:

29. Noir: Vol. 2: The Hit List
30. Bubblegum Crash Complete Collection: Total Crash

vcd
31. Tenchi Muyo 1-13
32. Plastic Little
33. The Gigolo
34. Adventure Duo 1-2
35. Fist of the north star
36. Macross 2
37. Urotsukidoji 3 parts 1,2,3, and 4.

I have disposed of my Vampire Hunter D disc after comparing it to the recently released version, and seeing very clearly how poor it was. I shall be getting the real version when i can.
As with Mad, any questions PM me, I'm not quite as helpful as him, but I'm ok. Also, all my disc's are R2, whereas Mad has only R1 (as far as I know).

Others i have got since my last amendmet to this list:

38.Spriggan
39.Samurai X:betral
40.Samurai X: Trust

All bold added in edit.

Let's see on DVD I have The Amon Saga, Transformers the Movie and Patlabor 1&2 although I hope to extend that collection over the next few years. I really want Ghost in The Shell and a few others I've seen in Trailers.

I have few DVDs

Manga

Patlabor 1
Patlabor 2
Neon Genesis Evangelion Collection 1
Neon Genesis Evangelion Collection 2
Neon Genesis Evangelion Collection 3
Neon Genesis Evangelion Collection 4
Neon Genesis Evangelion Death amd Rebirth
Neon Genesis Evangelion The End OF Evangelion
Samurai X Trust
Samurai X Betrayal
Detenator Orgun
Vampire Hunter D
Akira
Blood The Last Vampire
Ghost in the Shell
Perfect Blue
Vampire Wars
Ninja Scroll

Other Films

Final Fastasy The Spirits Within
Evolution
Harry Potter 1
Harry Potter 2
The Simpons Season 1
The Simpons Season 2
The Simpons Tree House of Horrors
Ace Venture Pet Dective
Crouching Tiger Hidden Dragon
Austin Powers in Goldmember
Rush Hour 2
Mortal Komat
Mortal Komat Conquest
Mortal Komat Conquest Final Battle
South Park The Movie
Resident Evil
8 Mile
The Fast and The Furious
The Matrix
The Matrix Revisited
The Animatrix
Gladitor
Monty Python and the quest for the holy grail
The One
Resoivor Dogs
Blade 2
Goodfelles
The Jackal

I don't really want to list all my anime but I will point out one thing...the top three anime movies I liked were

Princess Mononoke
Akira
X
thank you